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表4 干鱼腥草药材中新绿原酸等5种成分的加样回收 表5 干鱼腥草饮片中新绿原酸等5种成分的加样回收
率试验结果（n＝9） 率试验结果（n＝9）
待测成分 已知量/μg 加入量/μg 测得量/μg 加样回收率/％ 平均加样回收率/％ RSD/％ 待测成分 已知量/μg 加入量/μg 测得量/μg 加样回收率/％ 平均加样回收率/％ RSD/％
新绿原酸 489.216 245.128 737.102 101.13 99.63 0.99 新绿原酸 124.900 61.282 185.882 99.51 98.86 1.19
490.098 245.128 733.892 99.46 124.950 61.282 185.552 98.89
489.902 245.128 734.099 99.62 125.050 61.282 184.538 97.07
489.902 490.256 982.605 100.50 125.125 122.564 246.983 99.42
490.098 490.256 976.717 99.26 125.100 122.564 245.231 98.01
489.510 490.256 979.869 100.02 124.925 122.564 246.918 99.53
478.730 735.384 1 202.784 98.46 125.075 183.846 303.846 97.24
477.848 735.384 1 214.999 100.24 125.050 183.846 307.989 99.51
479.514 735.384 1 200.011 97.98 124.975 183.846 309.819 100.54
绿原酸 279.552 139.284 419.214 100.27 98.72 2.52 绿原酸 44.964 23.214 68.214 100.16 99.31 2.59
280.056 139.284 418.987 99.75 44.982 23.214 67.214 95.77
279.944 139.284 419.095 99.90 45.018 23.214 69.214 104.23
279.944 278.568 559.738 100.44 45.045 46.428 90.938 98.85
280.056 278.568 560.313 100.61 45.036 46.428 92.183 101.55
279.720 278.568 561.505 101.15 44.973 46.428 89.821 96.60
273.560 417.852 672.435 95.46 45.027 69.642 113.103 97.75
273.056 417.852 672.436 95.58 45.018 69.642 114.642 99.97
274.008 417.852 672.199 95.29 44.991 69.642 113.891 98.93
隐绿原酸 364.416 182.324 544.524 98.78 99.97 1.77 隐绿原酸 74.940 38.384 113.384 100.16 100.63 1.50
365.073 182.324 542.664 97.40 74.970 38.384 113.938 101.52
364.927 182.324 549.109 101.02 75.030 38.384 114.212 102.08
364.927 364.648 738.277 102.39 75.075 76.768 150.925 98.80
365.073 364.648 726.101 99.01 75.060 76.768 151.737 99.88
364.635 364.648 721.936 97.99 74.955 76.768 151.213 99.34
356.605 546.972 912.072 101.55 75.045 115.152 192.932 102.38
355.948 546.972 903.175 100.05 75.030 115.152 193.124 102.55
357.189 546.972 912.847 101.59 74.985 115.152 188.934 98.96
芦丁 294.528 146.880 440.642 99.48 101.12 1.67 芦丁 79.936 39.168 120.903 104.59 100.54 2.07
295.059 146.880 443.973 101.38 79.968 39.168 118.939 99.50
294.941 146.880 439.536 98.44 80.032 39.168 119.862 101.69
294.941 293.760 590.729 100.69 80.080 78.336 157.713 99.10
295.059 293.760 587.833 99.66 80.064 78.336 159.451 101.34
294.705 293.760 598.213 103.32 79.952 78.336 158.693 100.52
288.215 440.640 739.581 102.43 80.048 117.504 194.541 97.44
287.684 440.640 735.238 101.57 80.032 117.504 199.435 101.62
288.687 440.640 742.795 103.06 79.984 117.504 196.355 99.04
槲皮苷 3 060.096 1 532.952 4 597.081 100.26 100.03 0.15 槲皮苷 1 249.000 624.536 1 886.576 102.09 100.35 0.71
3 065.613 1 532.952 4 598.212 99.98 1 249.500 624.536 1 879.324 100.85
3 064.387 1 532.952 4 598.319 100.06 1 250.500 624.536 1 873.989 99.83
3 064.387 3 065.904 6 127.652 99.91 1 251.250 1 249.072 2 499.624 99.94
3 065.613 3 065.904 6 133.794 100.07 1 251.000 1 249.072 2 501.368 100.10
3 061.935 3 065.904 6 132.037 100.14 1 249.250 1 249.072 2 498.223 99.99
2 994.505 4 598.856 7 581.682 99.75 1 250.750 1 873.608 3 124.897 100.03
2 988.988 4 598.856 7 589.294 100.03 1 250.500 1 873.608 3 127.975 100.21
2 999.409 4 598.856 7 602.959 100.10 1 249.750 1 873.608 3 125.683 100.12
表6 10批干鱼腥草药材及10批饮片中新绿原酸等5种成分的含量测定结果（n＝3，mg/g）
药材/饮片 编号 新绿原酸 绿原酸 隐绿原酸 芦丁 槲皮苷 药材/饮片 编号 新绿原酸 绿原酸 隐绿原酸 芦丁 槲皮苷
药材 YC1 0.98 0.56 0.73 0.59 6.13 饮片 YP1 0.25 0.09 0.15 0.16 2.50
YC2 1.35 0.54 0.75 0.71 6.46 YP2 0.39 0.09 0.32 0.18 2.73
YC3 0.55 0.15 0.35 0.49 4.57 YP3 0.52 0.20 0.38 0.20 2.92
YC4 0.29 0.16 0.25 0.49 6.68 YP4 0.19 0.05 0.19 0.12 2.00
YC5 0.76 0.21 0.60 0.43 3.82 YP5 0.60 0.11 0.37 0.26 3.70
YC6 0.53 0.16 0.23 0.95 8.62 YP6 0.56 0.11 0.31 0.24 3.61
YC7 0.52 0.18 0.35 0.55 5.36 YP7 0.47 0.13 0.34 0.32 4.87
YC8 1.68 0.42 0.80 0.51 6.14 YP8 0.41 0.08 0.15 0.26 2.74
YC9 1.37 0.67 1.44 0.83 8.74 YP9 0.60 0.13 0.16 0.38 3.64
YC10 0.62 0.20 0.35 0.51 5.15 YP10 0.22 0.08 0.18 0.17 2.86
平均值 0.87 0.33 0.59 0.61 6.17 平均值 0.42 0.11 0.26 0.23 3.16
·928 · China Pharmacy 2022 Vol. 33 No. 8 中国药房 2022年第33卷第8期
